Zend certified PHP/Magento developer

Can libreoffice differentiate between files of same mime type based on extension?

Can libreoffice differentiate between files of the same mime type based on extension?
I have a two file’s that have a mime type of ‘plain text document’ text/plain detected.
One file ends in .txt and the other ends in .csv.
Is it possible to tell libreoffice to open .txt files with writer and .csv files with calc?
Thanks