Zend certified PHP/Magento developer

How to retrieve a server certificate by just knowing the root CA

I have a client application in production which make a TLS connexion to a server.

This server will get certified by a new CA in a short future (soon Amazon TrustStore service previously it was DigiCert).
For the moment it is still certified by DigiCert (openssl s_client -showcerts -connect ip:port return a certificate certified by DigiCert)

Is it possible to get the futur server certificate by requested Amazon truststore “repository” if the server is already registered near Amazon TrustStore service?