Zend certified PHP/Magento developer

UPS API throws error “Invalid Shipment content Value” for US country

I am using UPS API in Magento for CANADA and USA country,if I am passing same request parameters for Canada it working fine and get response as aspected but if I pass US address in <ShipTo> parameter in UPS API request ,it throws error invalid shipment contents value

Here is UPS API Request which is I am passing below request,it works fine for Canada address but it does not work for US address.

Can anyone address me what I am going to wrong below request for US address ?

Request

<AccessRequest xml:lang="en-US">    
  <AccessLicenseNumber>******</AccessLicenseNumber> 
  <UserId>*****</UserId>    
  <Password>*****</Password>    
</AccessRequest><?xml version="1.0"?>   
<RatingServiceSelectionRequest xml:lang="en-US">    
  <Request> 
    <TransactionReference>  
      <CustomerContext>Rating and Service</CustomerContext> 
      <XpciVersion>1.0</XpciVersion>    
    </TransactionReference> 
    <RequestAction>Rate</RequestAction> 
    <RequestOption>Shoptimeintransit</RequestOption>    
  </Request>    
  <PickupType>  
          <Code>01</Code>   
          <Description>Regular Daily Pickup</Description>   
  </PickupType> 
  <Shipment>      <Shipper><ShipperNumber>****</ShipperNumber>      <Address>   
          <City>Scarborough</City>  
          <PostalCode>M1G 0A6</PostalCode>  
          <CountryCode>CA</CountryCode> 
          <StateProvinceCode>ON</StateProvinceCode> 
      </Address>    
    </Shipper>  
    <ShipTo>    
      <Address> 
          <PostalCode>14304</PostalCode>    
          <CountryCode>US</CountryCode> 
          <ResidentialAddress>02</ResidentialAddress>   
          <StateProvinceCode>NY</StateProvinceCode>      </Address> 
    </ShipTo>   
    <ShipFrom>  
      <Address> 
          <PostalCode>M1G 0A6</PostalCode>  
          <CountryCode>CA</CountryCode> 
          <StateProvinceCode>ON</StateProvinceCode> 
      </Address>    
    </ShipFrom> 
    <DeliveryTimeInformation>   
    <PackageBillType>03</PackageBillType>   
</DeliveryTimeInformation>  
    <Package>   
      <PackagingType>   
        <Code>00</Code> 
      </PackagingType>  
      <PackageWeight>   
        <UnitOfMeasurement> 
          <Code>LBS</Code>  
        </UnitOfMeasurement>    
        <Weight>0.2</Weight>    
      </PackageWeight>  
    </Package>  
    <ShipmentTotalWeight>   
    <UnitOfMeasurement> 
        <Code>LBS</Code>    
    </UnitOfMeasurement>    
    <Weight>0.2</Weight>    
    </ShipmentTotalWeight><RateInformation><NegotiatedRatesIndicator/></RateInformation>      </Shipment>   
    </RatingServiceSelectionRequest>

RESPONSE

<RatingServiceSelectionResponse>
    <Response>
        <TransactionReference>
            <CustomerContext>Rating and Service</CustomerContext>
            <XpciVersion>1.0</XpciVersion>
        </TransactionReference>
        <ResponseStatusCode>0</ResponseStatusCode>
        <ResponseStatusDescription>Failure</ResponseStatusDescription>
        <Error>
            <ErrorSeverity>Hard</ErrorSeverity>
            <ErrorCode>111549</ErrorCode>
            <ErrorDescription>Invalid Shipment Contents Value.</ErrorDescription>
        </Error>
    </Response>
</RatingServiceSelectionResponse>